A chain was a series of linked metal loops used for various purposes.

When Sub-commander T'Pol suggested to use stun grenades, detonate them, and use both shuttlepods to bring the Novans back to Enterprise NX-01, Captain Jonathan Archer asked her what to do then with the Novans – put them in chains? T'Pol then stated that Mister Reed would devise appropriate restraints. This suggestion was dismissed by Archer as Enterprise was no slave ship. (ENT: "Terra Nova")

In 2266, Lenore Karidian compared the Karidian Company of Players's schedule to a chain, saying that if one link broke, the rest of it would collapse. (TOS: "The Conscience of the King")

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