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According to Gene Roddenberry, trititanium is the material from which the hull of the Enterprise is made of in his novelization of ST:TMP. ST:TNG also assumed trititanium to be what the hull of the Enterprise-D is made of, and also a general Starfleet hull-making material.

It's not clear if it's meant to be the same material as "tritanium" which TOS "Obsession" identifies as "20 times harder than diamond".

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