Anan 7's wife
The first woman, who wore a green dress, walked the same corridor that Mea 3 and her guards used, shortly before they greeted the Enterprise away team.
She, along with a woman in a colorful dress, and third in a purple dress, were later outside Disintegration Station 12, moments before it was destroyed by Kirk.
The High Council members were the governing body of the Eminian Union and the planet Eminiar VII at the time of James T. Kirk's visit in 2267. There were five members, who were led by Anan 7 who was the single High Councilor and spokesman. The Council's principal duties appeared to be prosecuting the centuries-long computerized war between Eminiar and its sister planet, Vendikar.
The first and fourth councilors later attended to the War Room as the Vendikar attacked, shortly after the arrival of the Enterprise. They indicated the need for Anan's presense in the War Room during the attack. (TOS: "A Taste of Armageddon")
These diplomatic escorts – one wearing a red sash and hat, the other wearing a purple sash and hat – was assigned to accompany Mea 3, an attaché to the Eminian High Council, when she was sent to meet a landing party from the starship Enterprise. Before arriving at the rendezvous location, they were instructed that the Starfleet officers were to be treated in a manner that was correct but nothing more.
After accompanying Mea 3 to a position near the rendezvous point, they were told by her exactly where the officers would materialize and was reminded of his instructions about the way they were to be treated. They subsequently stayed with Mea 3 as she met with the away team and led them to the Eminian High Council room, where he proceeded to assist in guarding the exit door while the away team met with Anan 7. (TOS: "A Taste of Armageddon")
Guard #1 – #2
Guard #3 – #4
Guard #5 – #6
These two guards were the remainder of the security detachment Anan 7 requested after the attack on the USS Enterprise by Vendikar. These two took Spock, Tamura, Galloway, and Osborne under arrest, and escorted them to a nearby room for detainment. (TOS: "A Taste of Armageddon")
The guard was assigned to guard James T. Kirk, Spock, and the remainder of the landing party after they were detained by the Eminian Union, until the Enterprise's crew reported for disintegration. Spock used limited telepathic abilities to plant a suggestion in the guard's mind to open the door where they were locked in. He was incapacitated and his uniform was stolen. (TOS: "A Taste of Armageddon")
This guard was approached by Spock in a corridor during an escape attempt. Spock explained that "there's a multi-legged creature crawling on your shoulder," before he reached toward him and applyed a neck pinch. (TOS: "A Taste of Armageddon")
The guard appeared from around a corner just as Spock incapacited another guard with a Vulcan nerve pinch.
The guard was part of the personnel that manned a disintegration station to vaporize Eminiar citizens who had been designed as killed in the war with Vendikar, which was fought with computer simulations. (TOS: "A Taste of Armageddon")
Guard #11 – 12
These two guards were near Anan's quarters, where they attacked James T. Kirk as he attempted to take Anan hostage.
Guard #12 – 13
This security officer informed Anan 7 that the Federation prisoners had attacked their guard, escaped, were armed, and had destroyed Disintegration Station 12 by disruptor fire. (TOS: "A Taste of Armageddon")
He then responded to Anan's directive to have the planetary disruptor banks lock on to and fire at the orbiting Enterprise, stating that they were locked onto target and standing by.
War Room technician