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Memory Alpha

Valo I was the inhabited first planet in the Valo system. Located in the Alpha Quadrant, this planet was on the outskirts of Cardassian territory. This M-class planet had at least three moons. During the Occupation of Bajor in the 24th century, Bajorans settled refugee camps on this planet.

In 2368, Bajoran Resistance leader Orta maintained his hidden base on Valo Ic, the third moon of Valo I. Based on a tip from Keeve Falor, the USS Enterprise-D traveled to Valo I and made contact with Orta, who informed them that the Bajorans were not responsible for the attack on Solarion IV. (TNG: "Ensign Ro")

This planet's quadrant of origin was inferred based on the position of the Cardassian Union in the star chart appearing in the Star Trek: Picard episode "Maps and Legends".
In the script, the pronunciation for Valo was "VAH-lo". [1]
In the Star Trek: Star Charts (p. 47) and Stellar Cartography: The Starfleet Reference Library ("Federation Historical Highlights, 2161-2385"), the Valos system was shown to be near the Federation-Cardassian border and, by the late 24th century, to be an independent system.

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